Introduction & Context

Steam-jet thermocompression is a critical unit operation in process engineering, particularly within evaporation and distillation systems. By utilizing a steam ejector, low-pressure process vapors are entrained and compressed to a higher pressure using high-velocity motive steam. This process effectively recovers latent heat that would otherwise be rejected to a condenser, significantly improving the energy efficiency of the plant. It is most commonly applied in falling-film evaporators for food processing, chemical concentration, and desalination, where it serves as a cost-effective alternative to mechanical vapor recompression (MVR).

Methodology & Formulas

The performance of a thermocompressor is governed by mass and energy conservation principles within the ejector control volume, and detailed calculations such as the steam‑jet ejector vacuum calculation can be used to determine the achievable vacuum levels. The following formulas define the thermodynamic state of the system:

The compression ratio (Rc) and expansion ratio (Rp) are defined by the operating pressures:

\[ R_{c} = \frac{P_{\text{discharge}}}{P_{\text{suction}}} \] \[ R_{p} = \frac{P_{\text{motive}}}{P_{\text{suction}}} \]

The mass balance for the ejector, based on a unit mass of motive steam, is determined by the entrainment ratio (ω):

\[ \dot{m}_{\text{suction}} = \omega \cdot \dot{m}_{\text{motive}} \] \[ \dot{m}_{\text{discharge}} = \dot{m}_{\text{motive}} + \dot{m}_{\text{suction}} \]

The enthalpy of the discharge stream (hdischarge) is calculated via the energy balance, assuming an adiabatic mixing process where kinetic energy conversion is internal to the ejector:

\[ h_{\text{discharge}} = \frac{(\dot{m}_{\text{motive}} \cdot h_{\text{motive}}) + (\dot{m}_{\text{suction}} \cdot h_{\text{suction}})}{\dot{m}_{\text{discharge}}} \]

The degree of superheat (ΔTsuperheat) in the discharge steam is derived from the excess enthalpy relative to the saturated vapor enthalpy (hg,discharge) at the discharge pressure:

\[ \Delta H = h_{\text{discharge}} - h_{g,\text{discharge}} \] \[ \Delta T_{\text{superheat}} = \frac{\Delta H}{C_{p,\text{steam}}} \]

The overall system performance is quantified by the steam economy (SE):

\[ SE = 1 + \omega \]
Parameter Condition/Constraint Limit/Threshold
Compression Ratio (Rc) Empirical Validity 1.5 ≤ Rc ≤ 8.0
Entrainment Ratio (ω) High Compression Limit ω < 1.0 if Rc > 2.5
Suction Pressure (Psuction) Triple Point Avoidance Psuction > 0.6 kPa
Discharge State Thermodynamic Phase If hdischarge > hg,discharge, steam is superheated